Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.200502532
Title: Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel
Authors: Weng, Z.
Teo, S.
Lip, L.K. 
Hor, T.S.A. 
Keywords: Coordination modes
Homogeneous catalysis
N,P ligands
Nickel
Oligomerization
Issue Date: 25-Nov-2005
Citation: Weng, Z., Teo, S., Lip, L.K., Hor, T.S.A. (2005-11-25). Ethylene oligomerization at coordinatively and electronically unsaturated low-valent nickel. Angewandte Chemie - International Edition 44 (46) : 7560-7564. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200502532
Abstract: (Chemical Equation Presented) Three modes: An iminoferrocenylphosphane ligand stabilizes low-coordinate and low-valent nickel in [{[η-C 5H4CH=N-(C6H5)]Fe[η-C 5H4P(tBu)2]-N,P}NiICl] (see figure) and similar complexes. The coordination environment is hemilabile as exemplified by three different coordination modes: P,N(σ)-chelate, P,CN(π)-chelate, and P unidentate. These complexes are catalytically active towards ethylene oligomerization. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/93771
ISSN: 14337851
DOI: 10.1002/anie.200502532
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