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https://doi.org/10.1002/anie.201202079
| Title: | Enantioselective bromolactonization using an S-alkyl thiocarbamate catalyst | Authors: | Jiang, X. Tan, C.K. Zhou, L. Yeung, Y.-Y. |
Keywords: | asymmetric catalysis cyclization lactones Lewis bases natural products |
Issue Date: | 27-Jul-2012 | Citation: | Jiang, X., Tan, C.K., Zhou, L., Yeung, Y.-Y. (2012-07-27). Enantioselective bromolactonization using an S-alkyl thiocarbamate catalyst. Angewandte Chemie - International Edition 51 (31) : 7771-7775. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201202079 | Abstract: | The apple never falls far from the tree: S-alkyl thiocarbamate 1 (see scheme, NBP=N-bromophthalimide) was prepared in high yield through a synthetic sequence involving a Newman-Kwart rearrangement of the corresponding O-alkyl thiocarbamates. Compound 1 was used to catalyze bromolactonization, thus providing enantioenriched δ-lactones in excellent yield and enantioselectivity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | Angewandte Chemie - International Edition | URI: | http://scholarbank.nus.edu.sg/handle/10635/93735 | ISSN: | 14337851 | DOI: | 10.1002/anie.201202079 |
| Appears in Collections: | Staff Publications |
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