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Title: Dissociation and [2+2]-like cycloaddition of unsaturated chain amines on Si(111)-7×7
Authors: Huang, J.Y.
Tang, H.H.
Shao, Y.X.
Liu, Q.P. 
Alshahateet, S.F.
Sun, Y.M.
Xu, G.Q. 
Issue Date: 10-May-2007
Citation: Huang, J.Y., Tang, H.H., Shao, Y.X., Liu, Q.P., Alshahateet, S.F., Sun, Y.M., Xu, G.Q. (2007-05-10). Dissociation and [2+2]-like cycloaddition of unsaturated chain amines on Si(111)-7×7. Journal of Physical Chemistry C 111 (18) : 6732-6739. ScholarBank@NUS Repository.
Abstract: The covalent attachment of N-methylallylamine (MAA) and N,N-dimethylallylamine (DMAA) on Si(111)-7×7 was investigated with high-resolution electron energy loss spectroscopy (HREELS) and X-ray photoelectron spectroscopy (XPS). Experimental results showed that MAA chemisorbs dissociatively on Si(111)-7×7 through the cleavage of its N-H bond, while DMAA is covalently bonded to the silicon surface via a [2+2]-like cycloaddition between its C=C group and the adjacent adatom-rest atom pair. This study demonstrates that the selective organic functionalization of silicon surfaces can be achieved by fine-tuning molecular structures. © 2007 American Chemical Society.
Source Title: Journal of Physical Chemistry C
ISSN: 19327447
DOI: 10.1021/jp067276z
Appears in Collections:Staff Publications

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