Please use this identifier to cite or link to this item: https://doi.org/10.1021/jp067276z
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dc.titleDissociation and [2+2]-like cycloaddition of unsaturated chain amines on Si(111)-7×7
dc.contributor.authorHuang, J.Y.
dc.contributor.authorTang, H.H.
dc.contributor.authorShao, Y.X.
dc.contributor.authorLiu, Q.P.
dc.contributor.authorAlshahateet, S.F.
dc.contributor.authorSun, Y.M.
dc.contributor.authorXu, G.Q.
dc.date.accessioned2014-10-16T08:26:23Z
dc.date.available2014-10-16T08:26:23Z
dc.date.issued2007-05-10
dc.identifier.citationHuang, J.Y., Tang, H.H., Shao, Y.X., Liu, Q.P., Alshahateet, S.F., Sun, Y.M., Xu, G.Q. (2007-05-10). Dissociation and [2+2]-like cycloaddition of unsaturated chain amines on Si(111)-7×7. Journal of Physical Chemistry C 111 (18) : 6732-6739. ScholarBank@NUS Repository. https://doi.org/10.1021/jp067276z
dc.identifier.issn19327447
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93618
dc.description.abstractThe covalent attachment of N-methylallylamine (MAA) and N,N-dimethylallylamine (DMAA) on Si(111)-7×7 was investigated with high-resolution electron energy loss spectroscopy (HREELS) and X-ray photoelectron spectroscopy (XPS). Experimental results showed that MAA chemisorbs dissociatively on Si(111)-7×7 through the cleavage of its N-H bond, while DMAA is covalently bonded to the silicon surface via a [2+2]-like cycloaddition between its C=C group and the adjacent adatom-rest atom pair. This study demonstrates that the selective organic functionalization of silicon surfaces can be achieved by fine-tuning molecular structures. © 2007 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/jp067276z
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/jp067276z
dc.description.sourcetitleJournal of Physical Chemistry C
dc.description.volume111
dc.description.issue18
dc.description.page6732-6739
dc.identifier.isiut000246190500023
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