Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2010.07.011

Title:	Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
Authors:	Ujam, O.T. Devoy, S.M. Henderson, W. Nicholson, B.K. Hor, T.S.A.
Keywords:	Alkylation reactions Crystal structure Platinum complexes Sulfido complexes Thiolate complexes
Issue Date:	25-Oct-2010
Citation:	Ujam, O.T., Devoy, S.M., Henderson, W., Nicholson, B.K., Hor, T.S.A. (2010-10-25). Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]. Inorganica Chimica Acta 363 (13) : 3558-3568. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2010.07.011
Abstract:	Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved.
Source Title:	Inorganica Chimica Acta
URI:	http://scholarbank.nus.edu.sg/handle/10635/93593
ISSN:	00201693
DOI:	10.1016/j.ica.2010.07.011
Appears in Collections:	Staff Publications

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