Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2010.07.011
Title: Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]
Authors: Ujam, O.T.
Devoy, S.M.
Henderson, W.
Nicholson, B.K.
Hor, T.S.A. 
Keywords: Alkylation reactions
Crystal structure
Platinum complexes
Sulfido complexes
Thiolate complexes
Issue Date: 25-Oct-2010
Source: Ujam, O.T., Devoy, S.M., Henderson, W., Nicholson, B.K., Hor, T.S.A. (2010-10-25). Dinuclear platinum complexes with designer thiolate ligands from the monoalkylation of [Pt2(μ-S)2(PPh3) 4]. Inorganica Chimica Acta 363 (13) : 3558-3568. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2010.07.011
Abstract: Alkylation reactions of the nucleophilic platinum(II) sulfide complex [Pt2(μ-S)2(PPh3)4] with functionalised alkylating agents have been investigated as a versatile synthetic route to dinuclear, cationic sulfide-thiolate complexes of the type [Pt 2(μ-S)(μ-SR)(PPh3)4]+, extending the range of thiolate complexes that can be prepared using this methodology. A wide range of functional groups can be incorporated, using appropriate alkylating agents, and include ketone, ester, amide, hydrazone, semicarbazone, thiosemicarbazone, oxime, guanidine, urea and thiourea groups. © 2010 Elsevier B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
URI: http://scholarbank.nus.edu.sg/handle/10635/93593
ISSN: 00201693
DOI: 10.1016/j.ica.2010.07.011
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

16
checked on Apr 3, 2018

WEB OF SCIENCETM
Citations

15
checked on Apr 3, 2018

Page view(s)

23
checked on Apr 20, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.