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| Title: | Conformation preferences of 1,1′bis(1-amino-4,4-dicyclopropyl-2,3-diaza-1,3-butadienyl) | Authors: | Lam, Y. Ma, N.L. Liang, E. |
Issue Date: | Apr-2001 | Citation: | Lam, Y., Ma, N.L., Liang, E. (2001-04). Conformation preferences of 1,1′bis(1-amino-4,4-dicyclopropyl-2,3-diaza-1,3-butadienyl). Bulletin of the Chemical Society of Japan 74 (4) : 699-700. ScholarBank@NUS Repository. | Abstract: | The reaction of dicyclopropyl ketone with hydrazine sulfate and sodium cyanide afforded 1,1′-bis(1-amino-4,4-dicyclopropyl-2,3-diaza-1,3-butadienyl). The compound exists in the trans conformation in the solid-state and has a trans population of 91.2% in solution. Experimental data are compared with values estimated by ab initio calculations. | Source Title: | Bulletin of the Chemical Society of Japan | URI: | http://scholarbank.nus.edu.sg/handle/10635/93354 | ISSN: | 00092673 |
| Appears in Collections: | Staff Publications |
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