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https://doi.org/10.1016/S1381-1169(97)00144-1
| Title: | Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes | Authors: | Wei, B. Li, S. Lee, H.K. Hor, T.S.A. |
Keywords: | Debromination Diphosphine Metallocenyl phosphine Palladium Polybromobenzenes |
Issue Date: | 10-Dec-1997 | Citation: | Wei, B., Li, S., Lee, H.K., Hor, T.S.A. (1997-12-10). Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes. Journal of Molecular Catalysis A: Chemical 126 (2-3) : L83-L88. ScholarBank@NUS Repository. https://doi.org/10.1016/S1381-1169(97)00144-1 | Abstract: | Pd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base. | Source Title: | Journal of Molecular Catalysis A: Chemical | URI: | http://scholarbank.nus.edu.sg/handle/10635/93340 | ISSN: | 13811169 | DOI: | 10.1016/S1381-1169(97)00144-1 |
| Appears in Collections: | Staff Publications |
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