Please use this identifier to cite or link to this item: https://doi.org/10.1016/S1381-1169(97)00144-1
Title: Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes
Authors: Wei, B.
Li, S. 
Lee, H.K. 
Hor, T.S.A. 
Keywords: Debromination
Diphosphine
Metallocenyl phosphine
Palladium
Polybromobenzenes
Issue Date: 10-Dec-1997
Citation: Wei, B., Li, S., Lee, H.K., Hor, T.S.A. (1997-12-10). Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes. Journal of Molecular Catalysis A: Chemical 126 (2-3) : L83-L88. ScholarBank@NUS Repository. https://doi.org/10.1016/S1381-1169(97)00144-1
Abstract: Pd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base.
Source Title: Journal of Molecular Catalysis A: Chemical
URI: http://scholarbank.nus.edu.sg/handle/10635/93340
ISSN: 13811169
DOI: 10.1016/S1381-1169(97)00144-1
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