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|Title:||Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes|
|Citation:||Wei, B., Li, S., Lee, H.K., Hor, T.S.A. (1997-12-10). Complete debromination of polybrominated benzenes at room temperature catalyzed by palladium metallocenyl diphosphine complexes. Journal of Molecular Catalysis A: Chemical 126 (2-3) : L83-L88. ScholarBank@NUS Repository. https://doi.org/10.1016/S1381-1169(97)00144-1|
|Abstract:||Pd-catalyzed reductive debromination of highly brominated benzenes is studied as a model for degradation of polybrominated biphenyls (PBBs). A complete conversion of hexabromobenzene to benzene at room temperature has been achieved. Both PdCl2[(C5H4PPh2)2M] (M = Fe, Ru) show excellent catalytic activities in the presence of NaBH4 as a reducing agent and Me2NC2H4NMe2 as a base.|
|Source Title:||Journal of Molecular Catalysis A: Chemical|
|Appears in Collections:||Staff Publications|
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