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Title: Anthracene-fused BODIPYs as near-infrared dyes with high photostability
Authors: Zeng, L.
Jiao, C.
Huang, X.
Huang, K.-W.
Chin, W.-S. 
Wu, J. 
Issue Date: 18-Nov-2011
Citation: Zeng, L., Jiao, C., Huang, X., Huang, K.-W., Chin, W.-S., Wu, J. (2011-11-18). Anthracene-fused BODIPYs as near-infrared dyes with high photostability. Organic Letters 13 (22) : 6026-6029. ScholarBank@NUS Repository.
Abstract: An anthracene unit was successfully fused to the zigzag edge of a boron dipyrromethene (BODIPY) core by an FeCl 3-mediated oxidative cyclodehydrogenation reaction. Meanwhile, a dimer was also formed by both intramolecular cyclization and intermolecular coupling. The anthracene-fused BODIPY monomer 7a and dimer 7b showed small energy gaps (∼1.4 eV) and near-infrared absorption/emission. Moreover, they exhibited high photostability. © 2011 American Chemical Society.
Source Title: Organic Letters
ISSN: 15237060
DOI: 10.1021/ol202493c
Appears in Collections:Staff Publications

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