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https://doi.org/10.1021/om0610445
| Title: | [Cp*IrCl2]2-assisted C=C bond cleavage with water: An experimental and computational study | Authors: | Sridevi, V.S. Wai, Y.F. Weng, K.L. |
Issue Date: | 26-Feb-2007 | Citation: | Sridevi, V.S., Wai, Y.F., Weng, K.L. (2007-02-26). [Cp*IrCl2]2-assisted C=C bond cleavage with water: An experimental and computational study. Organometallics 26 (5) : 1173-1177. ScholarBank@NUS Repository. https://doi.org/10.1021/om0610445 | Abstract: | Reaction of the dimeric species [Cp*IrCl2]2 with a number of organic substrates carrying a terminal alkyne functionality (RCCH) in the presence of water leads to C=C bond cleavage to form Cp*IrCl-(CH2R)(CO). The reaction pathway has been studied both experimentally and computationally. © 2007 American Chemical Society. | Source Title: | Organometallics | URI: | http://scholarbank.nus.edu.sg/handle/10635/92882 | ISSN: | 02767333 | DOI: | 10.1021/om0610445 |
| Appears in Collections: | Staff Publications |
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