Please use this identifier to cite or link to this item:
Title: Chemical and kinetic study of acetophenone hydrogenation over Pt/Al2O3: Application of BTEM and other multivariate techniques to quantitative on-line FTIR measurements
Authors: Gao, F.
Allian, A.D.
Zhang, H.
Cheng, S.
Garland, M. 
Keywords: BTEM/tBTEM
Heterogeneous catalysis
LHHW model
Multiple perturbations
On-line FTIR spectroscopy
Recycle reactor
Issue Date: 1-Jul-2006
Citation: Gao, F., Allian, A.D., Zhang, H., Cheng, S., Garland, M. (2006-07-01). Chemical and kinetic study of acetophenone hydrogenation over Pt/Al2O3: Application of BTEM and other multivariate techniques to quantitative on-line FTIR measurements. Journal of Catalysis 241 (1) : 189-199. ScholarBank@NUS Repository.
Abstract: The heterogeneous catalytic hydrogenation of acetophenone (Aceph) over Pt/Al2O3 in d8-toluene/h8-toluene at 273 K was performed in semibatch mode, using a recycle configuration and on-line quantitative Fourier transform infrared (FTIR) spectroscopy measurements. Based on the d8-toluene solvent used and the multivariate analysis applied, further details of the reaction chemistry were elucidated, including the following: (i) Solvent activation occurred during reaction, leading to observable hydrogenation and H-D exchange, and (ii) 1-phenylethanol (Phel), cyclohexyl methyl ketone (CMK), and cyclohexylethanol (Che) were observable products, and little H-D exchange occurred. The on-line FTIR measurements, with sensitivity on the order of 10-5   mol / L, also lead to the following kinetic observations: (i) Water had a strong inhibiting effect on the hydrogenation rates, and (ii) very interesting short time-scale kinetic behavior occurred after some perturbations. The latter included rapid initial hydrogenations on fresh catalyst (due to the presence of spillover hydrogen) and observable adsorption-desorption of other reactants. The reaction rates obtained from the well-defined experiments in h8-toluene were fit to a number of Langmuir-Hinshelwood-Hougen-Watson (LHHW) models, in which the effects of solvent and water were included. A model involving a pairwise addition of adsorbed dissociated hydrogen to the adsorbed substrate provided the best fit of the data. The regression of the kinetic data suggested that water made a statistically significant contribution to the competitive adsorption on the catalyst surface. In more general terms, the present contribution suggests the utility of detailed on-line liquid-phase spectroscopy together with multivariate techniques for exploratory studies of heterogeneous catalytic systems. © 2006 Elsevier Inc. All rights reserved.
Source Title: Journal of Catalysis
ISSN: 00219517
DOI: 10.1016/j.jcat.2006.04.024
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.


checked on Jun 12, 2021


checked on Jun 12, 2021

Page view(s)

checked on Jun 8, 2021

Google ScholarTM



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.