Studies towards total synthesis of antillatoxin: Synthesis of C1-C11 fragment

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4039(97)10827-9

Title:	Studies towards total synthesis of antillatoxin: Synthesis of C1-C11 fragment
Authors:	Loh, T.-P. Cao, G.-Q. Pei, J.
Issue Date:	12-Mar-1998
Citation:	Loh, T.-P., Cao, G.-Q., Pei, J. (1998-03-12). Studies towards total synthesis of antillatoxin: Synthesis of C1-C11 fragment. Tetrahedron Letters 39 (11) : 1457-1460. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(97)10827-9
Abstract:	Synthesis of the key intermediate (5) of Antillatoxin (1) is presented. The synthesis is based on the indium-mediated allylation of 2,4,6,6-tetramethyl-2,4-heptadienal (3) and methyl (Z)-2-(bromomethyl)-2-butenoate (4) in saturated ammonium chloride catalyzed by lanthanide triflate which afforded the corresponding product 2 in good yield and high syn selectivity.
Source Title:	Tetrahedron Letters
URI:	http://scholarbank.nus.edu.sg/handle/10635/77084
ISSN:	00404039
DOI:	10.1016/S0040-4039(97)10827-9
Appears in Collections:	Staff Publications

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