Graphene oxide and rose bengal: Oxidative C-H functionalisation of tertiary amines using visible light

Please use this identifier to cite or link to this item: https://doi.org/10.1039/c1gc15865a

Title:	Graphene oxide and rose bengal: Oxidative C-H functionalisation of tertiary amines using visible light
Authors:	Pan, Y. Wang, S. Kee, C.W. Dubuisson, E. Yang, Y. Loh, K.P. Tan, C.-H.
Issue Date:	Dec-2011
Citation:	Pan, Y., Wang, S., Kee, C.W., Dubuisson, E., Yang, Y., Loh, K.P., Tan, C.-H. (2011-12). Graphene oxide and rose bengal: Oxidative C-H functionalisation of tertiary amines using visible light. Green Chemistry 13 (12) : 3341-3344. ScholarBank@NUS Repository. https://doi.org/10.1039/c1gc15865a
Abstract:	Visible light induced oxidative C-H functionalisation of tertiary amines catalysed by the combination of graphene oxide and Rose Bengal was developed. This reaction avoids the use of stoichiometric amounts of peroxy compounds as terminal oxidants. This reaction is useful for tri-alkyl amines including chiral tertiary amines. Both cyanide and trifluoromethyl nucleophiles were shown to participate in this reaction, providing α-cyano- and α- trifluoromethylated tertiary amines. © 2011 The Royal Society of Chemistry.
Source Title:	Green Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/76257
ISSN:	14639262
DOI:	10.1039/c1gc15865a
Appears in Collections:	Staff Publications

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