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https://doi.org/10.1021/ja900582a
| Title: | Amino-lndanol catalyzed enantioselective reactions of 3-hydroxy-2-pyridones | Authors: | Julian, Y.-T.S. Tan, C.-H. |
Issue Date: | 27-May-2009 | Citation: | Julian, Y.-T.S., Tan, C.-H. (2009-05-27). Amino-lndanol catalyzed enantioselective reactions of 3-hydroxy-2-pyridones. Journal of the American Chemical Society 131 (20) : 6904-6905. ScholarBank@NUS Repository. https://doi.org/10.1021/ja900582a | Abstract: | A new bifunctional catalyst, chiral amino-indanol 1a, containing both Bronsted base and hydrogen bonding donor moieties, has been identified. It is easily prepared in a single step from commercially available amino-indanol. It was found to be an excellent catalyst for Diels-Alder reactions of both 3-hydroxy-2-pyridone and 3-hydroxy-2-pyrone. Various dienophiles including N-substituted maleimides were investigated. The Diels-Alder adducts were obtained in excellent yields and high enantioselectivities. Copyright © 2009 American Chemical Society. | Source Title: | Journal of the American Chemical Society | URI: | http://scholarbank.nus.edu.sg/handle/10635/75549 | ISSN: | 00027863 | DOI: | 10.1021/ja900582a |
| Appears in Collections: | Staff Publications |
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