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|Title:||Amino-lndanol catalyzed enantioselective reactions of 3-hydroxy-2-pyridones||Authors:||Julian, Y.-T.S.
|Issue Date:||27-May-2009||Citation:||Julian, Y.-T.S., Tan, C.-H. (2009-05-27). Amino-lndanol catalyzed enantioselective reactions of 3-hydroxy-2-pyridones. Journal of the American Chemical Society 131 (20) : 6904-6905. ScholarBank@NUS Repository. https://doi.org/10.1021/ja900582a||Abstract:||A new bifunctional catalyst, chiral amino-indanol 1a, containing both Bronsted base and hydrogen bonding donor moieties, has been identified. It is easily prepared in a single step from commercially available amino-indanol. It was found to be an excellent catalyst for Diels-Alder reactions of both 3-hydroxy-2-pyridone and 3-hydroxy-2-pyrone. Various dienophiles including N-substituted maleimides were investigated. The Diels-Alder adducts were obtained in excellent yields and high enantioselectivities. Copyright © 2009 American Chemical Society.||Source Title:||Journal of the American Chemical Society||URI:||http://scholarbank.nus.edu.sg/handle/10635/75549||ISSN:||00027863||DOI:||10.1021/ja900582a|
|Appears in Collections:||Staff Publications|
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