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|Title:||Interconversion and decomposition of furanones||Authors:||Xu, Z.P.
|Issue Date:||Apr-1999||Citation:||Xu, Z.P.,Mok, C.Y.,Chin, W.S.,Huang, H.H.,Li, S.,Huang, W. (1999-04). Interconversion and decomposition of furanones. Journal of the Chemical Society. Perkin Transactions 2 (4) : 725-729. ScholarBank@NUS Repository.||Abstract:||The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.||Source Title:||Journal of the Chemical Society. Perkin Transactions 2||URI:||http://scholarbank.nus.edu.sg/handle/10635/66634||ISSN:||03009580|
|Appears in Collections:||Staff Publications|
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