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https://scholarbank.nus.edu.sg/handle/10635/66634
Title: | Interconversion and decomposition of furanones | Authors: | Xu, Z.P. Mok, C.Y. Chin, W.S. Huang, H.H. Li, S. Huang, W. |
Issue Date: | Apr-1999 | Citation: | Xu, Z.P.,Mok, C.Y.,Chin, W.S.,Huang, H.H.,Li, S.,Huang, W. (1999-04). Interconversion and decomposition of furanones. Journal of the Chemical Society. Perkin Transactions 2 (4) : 725-729. ScholarBank@NUS Repository. | Abstract: | The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor. | Source Title: | Journal of the Chemical Society. Perkin Transactions 2 | URI: | http://scholarbank.nus.edu.sg/handle/10635/66634 | ISSN: | 03009580 |
Appears in Collections: | Staff Publications |
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