Net Toroidal Magnetic Moment in the Ground State of a {Dy-6}-Triethanolamine Ring

Please use this identifier to cite or link to this item: https://doi.org/10.1021/ja309211d

Title:	Net Toroidal Magnetic Moment in the Ground State of a {Dy-6}-Triethanolamine Ring
Authors:	Ungur, Liviu Langley, Stuart K Hooper, Thomas N Moubaraki, Boujemaa Brechin, Euan K Murray, Keith S Chibotaru, Liviu F
Keywords:	Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry SINGLE-MOLECULE MAGNET
Issue Date:	14-Nov-2012
Publisher:	AMER CHEMICAL SOC
Citation:	Ungur, Liviu, Langley, Stuart K, Hooper, Thomas N, Moubaraki, Boujemaa, Brechin, Euan K, Murray, Keith S, Chibotaru, Liviu F (2012-11-14). Net Toroidal Magnetic Moment in the Ground State of a {Dy-6}-Triethanolamine Ring. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 134 (45) : 18554-18557. ScholarBank@NUS Repository. https://doi.org/10.1021/ja309211d
Abstract:	A toroidal magnetic moment in the absence of conventional total magnetic moment is observed in a {Dy6} ring. The reason for the net toroidal arrangement of the local magnetic moments is the high symmetry of the complex in combination with strong intra-molecular dipolar interactions between Dy ions. The description of single-ion and inter-ion anisotropic magnetic interactions is achieved here for the first time fully ab initio, i.e., without use of phenomenological parameters. © 2012 American Chemical Society.
Source Title:	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
URI:	https://scholarbank.nus.edu.sg/handle/10635/228848
ISSN:	00027863 15205126
DOI:	10.1021/ja309211d
Appears in Collections:	Staff Publications Elements

File	Description	Size	Format	Access Settings	Version
Ungur_JACS_2012.pdf	Published version	264.22 kB	Adobe PDF	CLOSED	None
Ungur_JACS_2012_SI.pdf	Supporting information	397.59 kB	Adobe PDF	CLOSED	None

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