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https://doi.org/10.1103/PhysRevLett.109.246403
Title: | Negative g Factors, Berry Phases, and Magnetic Properties of Complexes | Authors: | Chibotaru, LF Ungur, L |
Keywords: | Science & Technology Physical Sciences Physics, Multidisciplinary Physics SINGLE-MOLECULE MAGNETS PARAMAGNETIC RESONANCE SMM BEHAVIOR ANISOTROPY ATOM |
Issue Date: | 11-Dec-2012 | Publisher: | AMER PHYSICAL SOC | Citation: | Chibotaru, LF, Ungur, L (2012-12-11). Negative g Factors, Berry Phases, and Magnetic Properties of Complexes. PHYSICAL REVIEW LETTERS 109 (24). ScholarBank@NUS Repository. https://doi.org/10.1103/PhysRevLett.109.246403 | Abstract: | It is shown that the sign of the product of three Zeeman splitting factors corresponding to the main magnetic axes defines the sign of the Berry phase of a (pseudo) spin in an applied magneic field. Ab initio calculations show that gXgYgZ<0 is often the case for lanthanide and transition metal complexes, while we prove that it is never achieved in S complexes with dominant second-order magnetic anisotropy. In the case of polynuclear compounds, it is argued that the signs of individual gi, i=X, Y, Z, on each metal site can be extracted from experiment. © 2012 American Physical Society. | Source Title: | PHYSICAL REVIEW LETTERS | URI: | https://scholarbank.nus.edu.sg/handle/10635/228840 | ISSN: | 00319007 10797114 |
DOI: | 10.1103/PhysRevLett.109.246403 |
Appears in Collections: | Staff Publications Elements |
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Chibotaru_PRL_2012.pdf | Published version | 618.18 kB | Adobe PDF | OPEN | None | View/Download |
Chibotaru_PRL_2012_SI.pdf | Supporting information | 427.11 kB | Adobe PDF | OPEN | None | View/Download |
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