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https://doi.org/10.1021/ic301115b
Title: | A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior | Authors: | Liu, Jun-Liang Yuan, Kang Leng, Ji-Dong Ungur, Liviu Wernsdorfer, Wolfgang Guo, Fu-Sheng Chibotaru, Liviu F Tong, Ming-Liang |
Keywords: | Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry MOLECULE-MAGNET MAGNETIZATION REVERSAL LANTHANIDE COMPLEXES CRYSTAL-STRUCTURES GROUND-STATE ZERO-FIELD SPIN RELAXATION LIGAND SYMMETRY |
Issue Date: | 6-Aug-2012 | Publisher: | AMER CHEMICAL SOC | Citation: | Liu, Jun-Liang, Yuan, Kang, Leng, Ji-Dong, Ungur, Liviu, Wernsdorfer, Wolfgang, Guo, Fu-Sheng, Chibotaru, Liviu F, Tong, Ming-Liang (2012-08-06). A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior. INORGANIC CHEMISTRY 51 (15) : 8538-8544. ScholarBank@NUS Repository. https://doi.org/10.1021/ic301115b | Abstract: | The field-induced blockage of magnetization behavior was first observed in an Yb III-based molecule with a trigonally distorted octahedral coordination environment. Ab initio calculations and micro-SQUID measurements were performed to demonstrate the exhibition of easy-plane anisotropy, suggesting the investigated complex is the first pure lanthanide field-induced single-ion magnet (field-induced SIM) of this type. Furthermore, we found the relaxation time obeys a power law instead of an exponential law, indicating that the relaxation process should be involved a direct process rather than an Orbach process. © 2012 American Chemical Society. | Source Title: | INORGANIC CHEMISTRY | URI: | https://scholarbank.nus.edu.sg/handle/10635/228834 | ISSN: | 00201669 1520510X |
DOI: | 10.1021/ic301115b |
Appears in Collections: | Staff Publications Elements |
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Liu_IC_2012.pdf | Published version | 439.72 kB | Adobe PDF | CLOSED | None | |
Liu_IC_2012.cif.txt | Supporting information | 28.71 kB | Text | CLOSED | None | |
Liu_IC_2012_SI.pdf | Supporting information | 520.05 kB | Adobe PDF | CLOSED | None |
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