Please use this identifier to cite or link to this item:
https://doi.org/10.1021/ic301115b
DC Field | Value | |
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dc.title | A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior | |
dc.contributor.author | Liu, Jun-Liang | |
dc.contributor.author | Yuan, Kang | |
dc.contributor.author | Leng, Ji-Dong | |
dc.contributor.author | Ungur, Liviu | |
dc.contributor.author | Wernsdorfer, Wolfgang | |
dc.contributor.author | Guo, Fu-Sheng | |
dc.contributor.author | Chibotaru, Liviu F | |
dc.contributor.author | Tong, Ming-Liang | |
dc.date.accessioned | 2022-07-19T10:28:31Z | |
dc.date.available | 2022-07-19T10:28:31Z | |
dc.date.issued | 2012-08-06 | |
dc.identifier.citation | Liu, Jun-Liang, Yuan, Kang, Leng, Ji-Dong, Ungur, Liviu, Wernsdorfer, Wolfgang, Guo, Fu-Sheng, Chibotaru, Liviu F, Tong, Ming-Liang (2012-08-06). A Six-Coordinate Ytterbium Complex Exhibiting Easy-Plane Anisotropy and Field-Induced Single-Ion Magnet Behavior. INORGANIC CHEMISTRY 51 (15) : 8538-8544. ScholarBank@NUS Repository. https://doi.org/10.1021/ic301115b | |
dc.identifier.issn | 00201669 | |
dc.identifier.issn | 1520510X | |
dc.identifier.uri | https://scholarbank.nus.edu.sg/handle/10635/228834 | |
dc.description.abstract | The field-induced blockage of magnetization behavior was first observed in an Yb III-based molecule with a trigonally distorted octahedral coordination environment. Ab initio calculations and micro-SQUID measurements were performed to demonstrate the exhibition of easy-plane anisotropy, suggesting the investigated complex is the first pure lanthanide field-induced single-ion magnet (field-induced SIM) of this type. Furthermore, we found the relaxation time obeys a power law instead of an exponential law, indicating that the relaxation process should be involved a direct process rather than an Orbach process. © 2012 American Chemical Society. | |
dc.language.iso | en | |
dc.publisher | AMER CHEMICAL SOC | |
dc.source | Elements | |
dc.subject | Science & Technology | |
dc.subject | Physical Sciences | |
dc.subject | Chemistry, Inorganic & Nuclear | |
dc.subject | Chemistry | |
dc.subject | MOLECULE-MAGNET | |
dc.subject | MAGNETIZATION REVERSAL | |
dc.subject | LANTHANIDE COMPLEXES | |
dc.subject | CRYSTAL-STRUCTURES | |
dc.subject | GROUND-STATE | |
dc.subject | ZERO-FIELD | |
dc.subject | SPIN | |
dc.subject | RELAXATION | |
dc.subject | LIGAND | |
dc.subject | SYMMETRY | |
dc.type | Article | |
dc.date.updated | 2022-07-15T01:35:04Z | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1021/ic301115b | |
dc.description.sourcetitle | INORGANIC CHEMISTRY | |
dc.description.volume | 51 | |
dc.description.issue | 15 | |
dc.description.page | 8538-8544 | |
dc.published.state | Published | |
Appears in Collections: | Staff Publications Elements |
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File | Description | Size | Format | Access Settings | Version | |
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Liu_IC_2012.pdf | Published version | 439.72 kB | Adobe PDF | CLOSED | None | |
Liu_IC_2012.cif.txt | Supporting information | 28.71 kB | Text | CLOSED | None | |
Liu_IC_2012_SI.pdf | Supporting information | 520.05 kB | Adobe PDF | CLOSED | None |
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