Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.201100438
Title: A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality
Authors: Feltham, Humphrey LC
Lan, Yanhua
Kloewer, Frederik
Ungur, Liviu 
Chibotaru, Liviu F
Powell, Annie K
Brooker, Sally
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
dysprosium
imine relaxation
macrocycle
magnetism
single-molecule magnet
SCHIFF-BASE MACROCYCLES
ANISOTROPIC BARRIER
CHAIN MAGNET
RELAXATION
COMPLEXES
BEHAVIOR
MAGNETIZATION
LIGANDS
ANALOGS
UNITS
Issue Date: 1-Apr-2011
Publisher: WILEY-V C H VERLAG GMBH
Citation: Feltham, Humphrey LC, Lan, Yanhua, Kloewer, Frederik, Ungur, Liviu, Chibotaru, Liviu F, Powell, Annie K, Brooker, Sally (2011-04-01). A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality. CHEMISTRY-A EUROPEAN JOURNAL 17 (16) : 4362-4365. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201100438
Abstract: Macrocyclic single-molecule magnet: The dynamic behavior of the tetranuclear zinc(II)-dysprosium(III) complex of the hexaimine [3+3] macrocycle (LPr)6- under an external DC field (1500 Oe) indicates that it is a single-molecule magnet (SMM). It is the first to contain a single lanthanide ion (in orange, see graphic) coordinated inside the cavity of a single macrocyclic ligand and thus represents a new class of SMM. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: CHEMISTRY-A EUROPEAN JOURNAL
URI: https://scholarbank.nus.edu.sg/handle/10635/228750
ISSN: 09476539
15213765
DOI: 10.1002/chem.201100438
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