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https://doi.org/10.1002/chem.201100438
| Title: | A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality | Authors: | Feltham, Humphrey LC Lan, Yanhua Kloewer, Frederik Ungur, Liviu Chibotaru, Liviu F Powell, Annie K Brooker, Sally |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry dysprosium imine relaxation macrocycle magnetism single-molecule magnet SCHIFF-BASE MACROCYCLES ANISOTROPIC BARRIER CHAIN MAGNET RELAXATION COMPLEXES BEHAVIOR MAGNETIZATION LIGANDS ANALOGS UNITS |
Issue Date: | 1-Apr-2011 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Feltham, Humphrey LC, Lan, Yanhua, Kloewer, Frederik, Ungur, Liviu, Chibotaru, Liviu F, Powell, Annie K, Brooker, Sally (2011-04-01). A Non-sandwiched Macrocyclic Monolanthanide Single-Molecule Magnet: The Key Role of Axiality. CHEMISTRY-A EUROPEAN JOURNAL 17 (16) : 4362-4365. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201100438 | Abstract: | Macrocyclic single-molecule magnet: The dynamic behavior of the tetranuclear zinc(II)-dysprosium(III) complex of the hexaimine [3+3] macrocycle (LPr)6- under an external DC field (1500 Oe) indicates that it is a single-molecule magnet (SMM). It is the first to contain a single lanthanide ion (in orange, see graphic) coordinated inside the cavity of a single macrocyclic ligand and thus represents a new class of SMM. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | CHEMISTRY-A EUROPEAN JOURNAL | URI: | https://scholarbank.nus.edu.sg/handle/10635/228750 | ISSN: | 09476539 15213765 |
DOI: | 10.1002/chem.201100438 |
| Appears in Collections: | Staff Publications Elements |
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| File | Description | Size | Format | Access Settings | Version | |
|---|---|---|---|---|---|---|
| Feltham_CEJ_2011.pdf | Published version | 522.36 kB | Adobe PDF | CLOSED | None | |
| Feltham_CEJ_2011_SI.pdf | Supporting information | 283.45 kB | Adobe PDF | CLOSED | None |
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