Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201100306
Title: A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers
Authors: Boeer, Angelika B
Barra, Anne-Laure
Chibotaru, Liviu F
Collison, David
McInnes, Eric JL
Mole, Richard A
Simeoni, Giovanna G
Timco, Grigore A
Ungur, Liviu 
Unruh, Tobias
Winpenny, Richard EP
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
cluster compounds
cobalt
EPR spectroscopy
inelastic neutron scattering
magnetic properties
INELASTIC NEUTRON-SCATTERING
SINGLE-MOLECULE MAGNETS
COBALT(II) CLUSTER
CO-3(II) MOIETY
COMPLEXES
SYSTEMS
Issue Date: 1-Jan-2011
Publisher: WILEY-V C H VERLAG GMBH
Citation: Boeer, Angelika B, Barra, Anne-Laure, Chibotaru, Liviu F, Collison, David, McInnes, Eric JL, Mole, Richard A, Simeoni, Giovanna G, Timco, Grigore A, Ungur, Liviu, Unruh, Tobias, Winpenny, Richard EP (2011-01-01). A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 50 (17) : 4007-4011. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201100306
Abstract: Structurally similar, magnetically diverse: The exchange and Zeeman parameters of two dimetallic, six-coordinate cobalt(II) compounds-i.e., with orbitally degenerate metal ions-have been determined by a combination of high-resolution EPR and INS spectroscopies, together with ab intio calculations. It is suggested that the correlation between the local crystal field about the CoII centers and the superexchange pathway controls the magnetic interaction. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
URI: https://scholarbank.nus.edu.sg/handle/10635/228731
ISSN: 14337851
15213773
DOI: 10.1002/anie.201100306
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