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https://doi.org/10.1002/anie.201100306
| Title: | A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers | Authors: | Boeer, Angelika B Barra, Anne-Laure Chibotaru, Liviu F Collison, David McInnes, Eric JL Mole, Richard A Simeoni, Giovanna G Timco, Grigore A Ungur, Liviu Unruh, Tobias Winpenny, Richard EP |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry cluster compounds cobalt EPR spectroscopy inelastic neutron scattering magnetic properties INELASTIC NEUTRON-SCATTERING SINGLE-MOLECULE MAGNETS COBALT(II) CLUSTER CO-3(II) MOIETY COMPLEXES SYSTEMS |
Issue Date: | 1-Jan-2011 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Boeer, Angelika B, Barra, Anne-Laure, Chibotaru, Liviu F, Collison, David, McInnes, Eric JL, Mole, Richard A, Simeoni, Giovanna G, Timco, Grigore A, Ungur, Liviu, Unruh, Tobias, Winpenny, Richard EP (2011-01-01). A Spectroscopic Investigation of Magnetic Exchange Between Highly Anisotropic Spin Centers. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 50 (17) : 4007-4011. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201100306 | Abstract: | Structurally similar, magnetically diverse: The exchange and Zeeman parameters of two dimetallic, six-coordinate cobalt(II) compounds-i.e., with orbitally degenerate metal ions-have been determined by a combination of high-resolution EPR and INS spectroscopies, together with ab intio calculations. It is suggested that the correlation between the local crystal field about the CoII centers and the superexchange pathway controls the magnetic interaction. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. | Source Title: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | URI: | https://scholarbank.nus.edu.sg/handle/10635/228731 | ISSN: | 14337851 15213773 |
DOI: | 10.1002/anie.201100306 |
| Appears in Collections: | Staff Publications Elements |
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| File | Description | Size | Format | Access Settings | Version | |
|---|---|---|---|---|---|---|
| Boeer_Angew_2011_SI.pdf | Supporting information | 189.06 kB | Adobe PDF | CLOSED | None | |
| Boeer_Angew_2011.pdf | Published version | 767.02 kB | Adobe PDF | CLOSED | None |
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