Please use this identifier to cite or link to this item:
https://doi.org/10.1002/anie.201002690
| Title: | An Octanuclear [(Cr4Dy4III)-Dy-III] 3d-4f Single-Molecule Magnet | Authors: | Rinck, Julia Novitchi, Ghenadie Van den Heuvel, Willem Ungur, Liviu Lan, Yanhua Wernsdorfer, Wolfgang Anson, Christopher E Chibotaru, Liviu F Powell, Annie K |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry anisotropy chromium lanthanides magnetic properties single-molecule magnets MAGNETIZATION COMPLEXES DY TB LN MANGANESE CLUSTERS BEHAVIOR DIMERS LH3 |
Issue Date: | 1-Jan-2010 | Publisher: | WILEY-V C H VERLAG GMBH | Citation: | Rinck, Julia, Novitchi, Ghenadie, Van den Heuvel, Willem, Ungur, Liviu, Lan, Yanhua, Wernsdorfer, Wolfgang, Anson, Christopher E, Chibotaru, Liviu F, Powell, Annie K (2010-01-01). An Octanuclear [(Cr4Dy4III)-Dy-III] 3d-4f Single-Molecule Magnet. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 49 (41) : 7583-7587. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201002690 | Abstract: | "Square-within-a-square": The first Cr-Dy single-molecule magnet (SMM) with an energy barrier to spin reorientation of 15 K is presented. The anisotropy in this octanuclear compound arises from the orientations of the four DyIII centers (dark blue), which, in conjunction with the contributions from the CrIII centers (green), leads to the SMM behavior. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA. | Source Title: | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | URI: | https://scholarbank.nus.edu.sg/handle/10635/228730 | ISSN: | 14337851 15213773 |
DOI: | 10.1002/anie.201002690 |
| Appears in Collections: | Staff Publications Elements |
Show full item record
Files in This Item:
| File | Description | Size | Format | Access Settings | Version | |
|---|---|---|---|---|---|---|
| Rinck_Angew_2010.cif.txt | Supporting information | 19.55 kB | Text | CLOSED | None | |
| Rinck_Angew_2010.pdf | Published version | 656.51 kB | Adobe PDF | CLOSED | None | |
| Rinck_Angew_2010_SI.pdf | Supporting information | 717.23 kB | Adobe PDF | CLOSED | None |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.