Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.201002690
Title: An Octanuclear [(Cr4Dy4III)-Dy-III] 3d-4f Single-Molecule Magnet
Authors: Rinck, Julia
Novitchi, Ghenadie
Van den Heuvel, Willem
Ungur, Liviu 
Lan, Yanhua
Wernsdorfer, Wolfgang
Anson, Christopher E
Chibotaru, Liviu F
Powell, Annie K
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
anisotropy
chromium
lanthanides
magnetic properties
single-molecule magnets
MAGNETIZATION
COMPLEXES
DY
TB
LN
MANGANESE
CLUSTERS
BEHAVIOR
DIMERS
LH3
Issue Date: 1-Jan-2010
Publisher: WILEY-V C H VERLAG GMBH
Citation: Rinck, Julia, Novitchi, Ghenadie, Van den Heuvel, Willem, Ungur, Liviu, Lan, Yanhua, Wernsdorfer, Wolfgang, Anson, Christopher E, Chibotaru, Liviu F, Powell, Annie K (2010-01-01). An Octanuclear [(Cr4Dy4III)-Dy-III] 3d-4f Single-Molecule Magnet. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 49 (41) : 7583-7587. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201002690
Abstract: "Square-within-a-square": The first Cr-Dy single-molecule magnet (SMM) with an energy barrier to spin reorientation of 15 K is presented. The anisotropy in this octanuclear compound arises from the orientations of the four DyIII centers (dark blue), which, in conjunction with the contributions from the CrIII centers (green), leads to the SMM behavior. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
URI: https://scholarbank.nus.edu.sg/handle/10635/228730
ISSN: 14337851
15213773
DOI: 10.1002/anie.201002690
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