Please use this identifier to cite or link to this item: https://doi.org/10.1039/c4dt00846d
Title: Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes
Authors: Batchelor, Luke J
Cimatti, Irene
Guillot, Regis
Tuna, Floriana
Wernsdorfer, Wolfgang
Ungur, Liviu 
Chibotaru, Liviu F
Campbell, Victoria E
Mallaha, Talal
Keywords: Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
SINGLE-MOLECULE-MAGNET
ANISOTROPY
BEHAVIOR
TB
Issue Date: 28-Aug-2014
Publisher: ROYAL SOC CHEMISTRY
Citation: Batchelor, Luke J, Cimatti, Irene, Guillot, Regis, Tuna, Floriana, Wernsdorfer, Wolfgang, Ungur, Liviu, Chibotaru, Liviu F, Campbell, Victoria E, Mallaha, Talal (2014-08-28). Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes. DALTON TRANSACTIONS 43 (32) : 12146-12149. ScholarBank@NUS Repository. https://doi.org/10.1039/c4dt00846d
Abstract: A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. © 2014 the Partner Organisations.
Source Title: DALTON TRANSACTIONS
URI: https://scholarbank.nus.edu.sg/handle/10635/228715
ISSN: 1477-9226
1477-9234
DOI: 10.1039/c4dt00846d
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