Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes

Please use this identifier to cite or link to this item: https://doi.org/10.1039/c4dt00846d

Title:	Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes
Authors:	Batchelor, Luke J Cimatti, Irene Guillot, Regis Tuna, Floriana Wernsdorfer, Wolfgang Ungur, Liviu Chibotaru, Liviu F Campbell, Victoria E Mallaha, Talal
Keywords:	Science & Technology Physical Sciences Chemistry, Inorganic & Nuclear Chemistry SINGLE-MOLECULE-MAGNET ANISOTROPY BEHAVIOR TB
Issue Date:	28-Aug-2014
Publisher:	ROYAL SOC CHEMISTRY
Citation:	Batchelor, Luke J, Cimatti, Irene, Guillot, Regis, Tuna, Floriana, Wernsdorfer, Wolfgang, Ungur, Liviu, Chibotaru, Liviu F, Campbell, Victoria E, Mallaha, Talal (2014-08-28). Chemical tuning of the magnetic relaxation in dysprosium(III) mononuclear complexes. DALTON TRANSACTIONS 43 (32) : 12146-12149. ScholarBank@NUS Repository. https://doi.org/10.1039/c4dt00846d
Abstract:	A dysprosium(iii) complex, exhibiting slow relaxation of magnetization, was prepared. Crystallographic studies showed a perturbation of local symmetry upon deprotonation of the ligand, with concomitant faster relaxation of magnetization. This was attributed to a large shift in the direction of the main magnetic axis, as indicated by ab initio calculations. © 2014 the Partner Organisations.
Source Title:	DALTON TRANSACTIONS
URI:	https://scholarbank.nus.edu.sg/handle/10635/228715
ISSN:	1477-9226 1477-9234
DOI:	10.1039/c4dt00846d
Appears in Collections:	Staff Publications Elements

File	Description	Size	Format	Access Settings	Version
Batchelor_DT_2014.pdf	Published version	624.82 kB	Adobe PDF	CLOSED	None
Batchelor_DT_2014.cif.txt	Supporting information	73.83 kB	Text	CLOSED	None
Batchelor_DT_2014_SI.pdf	Supporting information	1.65 MB	Adobe PDF	CLOSED	None

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