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https://doi.org/10.1002/anie.201704579
| Title: | Oriented Two-Dimensional Porous Organic Cage Crystals | Authors: | Jiang, S Song, Q Massey, A Chong, S.Y Chen, L Sun, S Hasell, T Raval, R Sivaniah, E Cheetham, A.K Cooper, A.I |
Keywords: | Crystal growth Crystal orientation Defects Membranes Microporous materials Molecular crystals Porous silicon Silicon wafers Computational technique Defect concentrations Molecular separation Porous organic cages Preferred orientations Separation membranes Tetrahedral molecules Two Dimensional (2 D) Crystal defects |
Issue Date: | 2017 | Citation: | Jiang, S, Song, Q, Massey, A, Chong, S.Y, Chen, L, Sun, S, Hasell, T, Raval, R, Sivaniah, E, Cheetham, A.K, Cooper, A.I (2017). Oriented Two-Dimensional Porous Organic Cage Crystals. Angewandte Chemie - International Edition 56 (32) : 9391-9395. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.201704579 | Rights: | Attribution 4.0 International | Abstract: | The formation of two-dimensional (2D) oriented porous organic cage crystals (consisting of imine-based tetrahedral molecules) on various substrates (such as silicon wafers and glass) by solution-processing is reported. Insight into the crystallinity, preferred orientation, and cage crystal growth was obtained by experimental and computational techniques. For the first time, structural defects in porous molecular materials were observed directly and the defect concentration could be correlated with crystal growth rate. These oriented crystals suggest potential for future applications, such as solution-processable molecular crystalline 2D membranes for molecular separations. © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. | Source Title: | Angewandte Chemie - International Edition | URI: | https://scholarbank.nus.edu.sg/handle/10635/181310 | ISSN: | 14337851 | DOI: | 10.1002/anie.201704579 | Rights: | Attribution 4.0 International |
| Appears in Collections: | Elements Staff Publications |
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