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https://doi.org/10.1039/c5cc07977b
| Title: | Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf) | Authors: | Wong, V.H.L White, A.J.P Hor, T.S.A Hii, K.K |
Keywords: | bromide ion carbene chloride heterocyclic compound imidazolidine derivative iodide iodide ion oxygen silver Article carbon nuclear magnetic resonance chemical binding chemical structure cyclization energy synthesis X ray crystallography X ray diffraction |
Issue Date: | 2015 | Publisher: | Royal Society of Chemistry | Citation: | Wong, V.H.L, White, A.J.P, Hor, T.S.A, Hii, K.K (2015). Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf). Chemical Communications 51 (100) : 17752-17755. ScholarBank@NUS Repository. https://doi.org/10.1039/c5cc07977b | Abstract: | A series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC ? M ?-back-donation, which influences the stability and sigma-donicity of these complexes. © 2015 The Royal Society of Chemistry. | Source Title: | Chemical Communications | URI: | https://scholarbank.nus.edu.sg/handle/10635/175293 | ISSN: | 1359-7345 | DOI: | 10.1039/c5cc07977b |
| Appears in Collections: | Staff Publications Elements |
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