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Please use this identifier to cite or link to this item: https://doi.org/10.1039/c5cc07977b
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dc.titleStructure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf)
dc.contributor.authorWong, V.H.L
dc.contributor.authorWhite, A.J.P
dc.contributor.authorHor, T.S.A
dc.contributor.authorHii, K.K
dc.date.accessioned2020-09-09T07:20:22Z
dc.date.available2020-09-09T07:20:22Z
dc.date.issued2015
dc.identifier.citationWong, V.H.L, White, A.J.P, Hor, T.S.A, Hii, K.K (2015). Structure and bonding of [(SIPr)AgX] (X = Cl, Br, i and OTf). Chemical Communications 51 (100) : 17752-17755. ScholarBank@NUS Repository. https://doi.org/10.1039/c5cc07977b
dc.identifier.issn1359-7345
dc.identifier.urihttps://scholarbank.nus.edu.sg/handle/10635/175293
dc.description.abstractA series of iso-structural complexes [(SIPr)AgX] (X = Cl, Br, I, OTf; SIPr = 1,3-bis(2,6-diisopropylphenyl)imidazolidene) were synthesised, including the first example of a N-heterocyclic carbene silver(i) complex containing an O-bound triflate. Bond Energy Dissociation and Natural Orbitals for Chemical Valence bond analyses (BEDA & ETS-NOCV) revealing a significant NHC ? M ?-back-donation, which influences the stability and sigma-donicity of these complexes. © 2015 The Royal Society of Chemistry.
dc.publisherRoyal Society of Chemistry
dc.sourceUnpaywall 20200831
dc.subjectbromide ion
dc.subjectcarbene
dc.subjectchloride
dc.subjectheterocyclic compound
dc.subjectimidazolidine derivative
dc.subjectiodide
dc.subjectiodide ion
dc.subjectoxygen
dc.subjectsilver
dc.subjectArticle
dc.subjectcarbon nuclear magnetic resonance
dc.subjectchemical binding
dc.subjectchemical structure
dc.subjectcyclization
dc.subjectenergy
dc.subjectsynthesis
dc.subjectX ray crystallography
dc.subjectX ray diffraction
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/c5cc07977b
dc.description.sourcetitleChemical Communications
dc.description.volume51
dc.description.issue100
dc.description.page17752-17755
dc.published.statePublished
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