Please use this identifier to cite or link to this item: https://doi.org/10.1039/c7ce00344g
Title: Isoreticular covalent organic frameworks for hydrocarbon uptake and separation: the important role of monomer planarity
Authors: Dong, Jinqiao 
Wang, Yuxiang
Liu, Guoliang
Cheng, Youdong
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Crystallography
Chemistry
ROOM-TEMPERATURE
PROTON CONDUCTION
DIFFERENT KINDS
ENERGY-STORAGE
CRYSTALLINE
CONSTRUCTION
CATALYSIS
RECOGNITION
SELECTIVITY
EFFICIENT
Issue Date: 7-Sep-2017
Publisher: ROYAL SOC CHEMISTRY
Citation: Dong, Jinqiao, Wang, Yuxiang, Liu, Guoliang, Cheng, Youdong, Zhao, Dan (2017-09-07). Isoreticular covalent organic frameworks for hydrocarbon uptake and separation: the important role of monomer planarity. CRYSTENGCOMM 19 (33) : 4899-4904. ScholarBank@NUS Repository. https://doi.org/10.1039/c7ce00344g
Abstract: © 2017 The Royal Society of Chemistry. Covalent organic frameworks (COFs) represent a new class of crystalline porous organic materials with huge potential in gas storage and separation. Here we present three isoreticular COFs sharing identical two-dimensional layered structures but with different planarity of the building monomers, leading to various crystallinities, porosities and hydrocarbon uptake and separation performances. This study reveals the importance of monomer design in the long-range stacking of COFs, which can be used to tailor COFs with target functionalities for specific applications.
Source Title: CRYSTENGCOMM
URI: https://scholarbank.nus.edu.sg/handle/10635/170636
ISSN: 1466-8033
DOI: 10.1039/c7ce00344g
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