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https://doi.org/10.1039/c7cc04313a
| Title: | Structural-failure resistance of metal-organic frameworks toward multiple-cycle CO2 sorption | Authors: | Hu, Zhigang Sun, Yao Zeng, Kaiyang Zhao, Dan |
Keywords: | Science & Technology Physical Sciences Chemistry, Multidisciplinary Chemistry MECHANICAL-PROPERTIES CHEMICAL-STRUCTURE FACILE SYNTHESIS CU-BTC CAPTURE HYDROCARBON BEHAVIOR STORAGE UIO-66 |
Issue Date: | 11-Aug-2017 | Publisher: | ROYAL SOC CHEMISTRY | Citation: | Hu, Zhigang, Sun, Yao, Zeng, Kaiyang, Zhao, Dan (2017-08-11). Structural-failure resistance of metal-organic frameworks toward multiple-cycle CO2 sorption. CHEMICAL COMMUNICATIONS 53 (62) : 8653-8656. ScholarBank@NUS Repository. https://doi.org/10.1039/c7cc04313a | Abstract: | © 2017 The Royal Society of Chemistry. We present the first study on the structural-failure of MOFs induced by multiple-cycle CO2 adsorption and desorption, wherein UiO-66(Zr) demonstrates a much better resistance than HKUST-1 in 500-cycle CO2 adsorption-desorption tests. This conclusion is supported by the higher elastic modulus of UiO-66(Zr) (ca. 28 GPa) and retention of elastic modulus (100%) than HKUST-1 (ca. 19 GPa, 64%) measured via multifrequency atomic force microscopy (MAFM). | Source Title: | CHEMICAL COMMUNICATIONS | URI: | https://scholarbank.nus.edu.sg/handle/10635/170269 | ISSN: | 13597345 1364548X |
DOI: | 10.1039/c7cc04313a |
| Appears in Collections: | Staff Publications Elements |
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|---|---|---|---|---|---|---|
| Zhao_2017_CC_Structure Failure Resistance of MOFs_manuscript_02.docx | Accepted version | 7.3 MB | Microsoft Word XML | OPEN | Post-print | View/Download |
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