Please use this identifier to cite or link to this item: https://doi.org/10.1021/jacs.8b03517
Title: Process-Tracing Study on the Postassembly Modification of Highly Stable Zirconium Metal-Organic Cages
Authors: Liu, Guoliang 
Yuan, Yi Di 
Wang, Jian:rp04035 
Cheng, Youdong 
Peh, Shing Bo 
Wang, Yuxiang
Qian, Yuhong 
Dong, Jinqiao 
Yuan, Daqiang
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
POST-ASSEMBLY MODIFICATION
COORDINATION CAGES
CHEMISTRY
FUNCTIONALIZATION
CONSTRUCTION
TETRAHEDRON
POLYHEDRA
ION
Issue Date: 23-May-2018
Publisher: AMER CHEMICAL SOC
Citation: Liu, Guoliang, Yuan, Yi Di, Wang, Jian:rp04035, Cheng, Youdong, Peh, Shing Bo, Wang, Yuxiang, Qian, Yuhong, Dong, Jinqiao, Yuan, Daqiang, Zhao, Dan (2018-05-23). Process-Tracing Study on the Postassembly Modification of Highly Stable Zirconium Metal-Organic Cages. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 140 (20) : 6231-6234. ScholarBank@NUS Repository. https://doi.org/10.1021/jacs.8b03517
Abstract: © 2018 American Chemical Society. Metal-organic cages (MOCs) are discrete molecular assemblies formed by coordination bonds between metal nodes and organic ligands. The application of MOCs has been greatly limited due to their poor stability, especially in aqueous solutions. In this work, we thoroughly investigate the stability of several Zr-MOCs and reveal their excellent stability in aqueous solutions with acidic, neutral, and weak basic conditions. In addition, we present for the first time a process-tracing study on the postassembly modification of one MOC, ZrT-1-NH2, highlighting the excellent stability and versatility of Zr-MOCs as a new type of molecular platform for various applications.
Source Title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
URI: https://scholarbank.nus.edu.sg/handle/10635/169728
ISSN: 0002-7863
1520-5126
DOI: 10.1021/jacs.8b03517
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