Please use this identifier to cite or link to this item: https://doi.org/10.1039/c8dt05060k
Title: Cluster nuclearity control and modulated hydrothermal synthesis of functionalized Zr-12 metal-organic frameworks
Authors: Peh, Shing Bo 
Cheng, Youdong 
Zhang, Jian 
Wang, Yuxiang 
Chan, Ger Hui
Wang, Jian 
Zhao, Dan 
Keywords: Science & Technology
Physical Sciences
Chemistry, Inorganic & Nuclear
Chemistry
MISSING-LINKER DEFECTS
UIO-66
ACID
MOFS
ZR
Issue Date: 7-Jun-2019
Publisher: ROYAL SOCIETY OF CHEMISTRY
Citation: Peh, Shing Bo, Cheng, Youdong, Zhang, Jian, Wang, Yuxiang, Chan, Ger Hui, Wang, Jian, Zhao, Dan (2019-06-07). Cluster nuclearity control and modulated hydrothermal synthesis of functionalized Zr-12 metal-organic frameworks. DALTON TRANSACTIONS 48 (21) : 7069-7073. ScholarBank@NUS Repository. https://doi.org/10.1039/c8dt05060k
Abstract: © 2019 The Royal Society of Chemistry. The synthesis of chemically stable metal-organic frameworks (MOFs) in benign solvents is a key step towards their scalable production and commercialization. Extending the modulated hydrothermal (MHT) synthesis approach for zirconium (Zr) MOFs, we herein demonstrate cluster nuclearity control over the secondary building units (SBUs) to target Zr6-based and Zr12-based phases for the Zr terephthalate (Zr-BDC) system. Different functional groups (-NH2, -NO2, -Br, -F4) can be incorporated into Zr12-BDC, providing an avenue to further tune the chemical properties of these promising MOFs.
Source Title: DALTON TRANSACTIONS
URI: https://scholarbank.nus.edu.sg/handle/10635/169568
ISSN: 14779226
14779234
DOI: 10.1039/c8dt05060k
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