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|Title:||Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations|
|Authors:||Hor, T.S.A. |
|Source:||Hor, T.S.A.,Chee, S.-M. (1987-09-01). Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations. Journal of Organometallic Chemistry 331 (1) : 23-28. ScholarBank@NUS Repository.|
|Abstract:||The ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987.|
|Source Title:||Journal of Organometallic Chemistry|
|Appears in Collections:||Staff Publications|
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