Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/94949
DC Field | Value | |
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dc.title | Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations | |
dc.contributor.author | Hor, T.S.A. | |
dc.contributor.author | Chee, S.-M. | |
dc.date.accessioned | 2014-10-16T08:42:02Z | |
dc.date.available | 2014-10-16T08:42:02Z | |
dc.date.issued | 1987-09-01 | |
dc.identifier.citation | Hor, T.S.A.,Chee, S.-M. (1987-09-01). Substituted metal carbonyls. III. Chromium, molybdenum and tungsten tricarbonyl complexes containing bipyridyl and a unidentate diphosphine: facile synthesis via trimethylamine N-oxide-induced decarbonylations. Journal of Organometallic Chemistry 331 (1) : 23-28. ScholarBank@NUS Repository. | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94949 | |
dc.description.abstract | The ability of trimethylamine N-oxide as a chemical initiator for facile oxidative decarbonylation in metal carbonyls is manifested by the isolation of M(CO)3(η2-bipy)(η1-dppm) (where M Cr, Mo, W; bipy = 2,2′-bipyridyl; dppm = bis(diphenylphosphino)-methane). The synthetic strategy and spectral (IR and 1H and 31P NMR) characterisations are presented and discussed. Syntheses of the well-known M(CO)4(η2-bipy) have also been modified to give high yields at ambient temperature. © 1987. | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Journal of Organometallic Chemistry | |
dc.description.volume | 331 | |
dc.description.issue | 1 | |
dc.description.page | 23-28 | |
dc.description.coden | JORCA | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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