Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2004.11.014
Title: Reaction of the heterometallic cluster Os3Ru(μ-H) 2(CO)13 with diphenylphosphine: Phosphido-bridged tetrahedral and butterfly clusters
Authors: Pereira, L.J.
Chan, K.S.
Leong, W.K. 
Keywords: Clusters
Heteronuclear
Osmium
Phosphido
Ruthenium
Issue Date: 14-Feb-2005
Citation: Pereira, L.J., Chan, K.S., Leong, W.K. (2005-02-14). Reaction of the heterometallic cluster Os3Ru(μ-H) 2(CO)13 with diphenylphosphine: Phosphido-bridged tetrahedral and butterfly clusters. Journal of Organometallic Chemistry 690 (4) : 1033-1043. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2004.11.014
Abstract: TMNO-activated reaction of the heteronuclear cluster Os3Ru(μ- H)2(CO)13 (1) with diphenylphosphine afforded the novel phosphido-bridged clusters Os3Ru(μ-PPh2)(μ-H) 3(CO)11 (2), Os3Ru(μ-PPh2) 2(μ-H)2(CO)10 (3), Os3Ru(μ- PPh2)2(μ-H)4(CO)9 (4), and Os3Ru(μ-PPh2)(μ-H)3(CO) 11(PPh2H) (5). The formation of 2-5 proceeded via P-H bond cleavage in the adduct Os3Ru(μ-H)2(CO) 12(PPh2H) (6). Reaction of 2 with PPh3 afforded the adduct Os3Ru(μ-PPh2)(μ-H)3(CO) 11(PPh3) (7) and the substituted derivative Os 3Ru(μ-PPh2)(μ-H)3(CO) 10(PPh3) (8). © 2004 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/94663
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2004.11.014
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