Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.jorganchem.2004.11.014
DC Field | Value | |
---|---|---|
dc.title | Reaction of the heterometallic cluster Os3Ru(μ-H) 2(CO)13 with diphenylphosphine: Phosphido-bridged tetrahedral and butterfly clusters | |
dc.contributor.author | Pereira, L.J. | |
dc.contributor.author | Chan, K.S. | |
dc.contributor.author | Leong, W.K. | |
dc.date.accessioned | 2014-10-16T08:38:40Z | |
dc.date.available | 2014-10-16T08:38:40Z | |
dc.date.issued | 2005-02-14 | |
dc.identifier.citation | Pereira, L.J., Chan, K.S., Leong, W.K. (2005-02-14). Reaction of the heterometallic cluster Os3Ru(μ-H) 2(CO)13 with diphenylphosphine: Phosphido-bridged tetrahedral and butterfly clusters. Journal of Organometallic Chemistry 690 (4) : 1033-1043. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2004.11.014 | |
dc.identifier.issn | 0022328X | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94663 | |
dc.description.abstract | TMNO-activated reaction of the heteronuclear cluster Os3Ru(μ- H)2(CO)13 (1) with diphenylphosphine afforded the novel phosphido-bridged clusters Os3Ru(μ-PPh2)(μ-H) 3(CO)11 (2), Os3Ru(μ-PPh2) 2(μ-H)2(CO)10 (3), Os3Ru(μ- PPh2)2(μ-H)4(CO)9 (4), and Os3Ru(μ-PPh2)(μ-H)3(CO) 11(PPh2H) (5). The formation of 2-5 proceeded via P-H bond cleavage in the adduct Os3Ru(μ-H)2(CO) 12(PPh2H) (6). Reaction of 2 with PPh3 afforded the adduct Os3Ru(μ-PPh2)(μ-H)3(CO) 11(PPh3) (7) and the substituted derivative Os 3Ru(μ-PPh2)(μ-H)3(CO) 10(PPh3) (8). © 2004 Elsevier B.V. All rights reserved. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2004.11.014 | |
dc.source | Scopus | |
dc.subject | Clusters | |
dc.subject | Heteronuclear | |
dc.subject | Osmium | |
dc.subject | Phosphido | |
dc.subject | Ruthenium | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1016/j.jorganchem.2004.11.014 | |
dc.description.sourcetitle | Journal of Organometallic Chemistry | |
dc.description.volume | 690 | |
dc.description.issue | 4 | |
dc.description.page | 1033-1043 | |
dc.description.coden | JORCA | |
dc.identifier.isiut | 000227107500024 | |
Appears in Collections: | Staff Publications |
Show simple item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.