Group 15 ligand migration in the heteronuclear clusters RuOs 3(μ-H)2(CO)12(EPh3) (E = P, As, Sb)

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2006.01.007

Title:	Group 15 ligand migration in the heteronuclear clusters RuOs 3(μ-H)2(CO)12(EPh3) (E = P, As, Sb)
Authors:	Pereira, L.J. Leong, W.K.
Keywords:	Chemical exchange Group 15 ligand Heterometallic complexes Ligand migration Osmium Ruthenium
Issue Date:	15-Apr-2006
Citation:	Pereira, L.J., Leong, W.K. (2006-04-15). Group 15 ligand migration in the heteronuclear clusters RuOs 3(μ-H)2(CO)12(EPh3) (E = P, As, Sb). Journal of Organometallic Chemistry 691 (9) : 1941-1944. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2006.01.007
Abstract:	The monosubstituted clusters RuOs3(μ-H)2(CO) 12(EPh3) (where E = P, As, Sb) exhibit isomers in which the group 15 ligand is on an Os or an Ru vertex. Evidence is presented for hydride fluxionality and EPh3 ligand migration. These processes have been examined by variable temperature NMR studies, and the kinetic parameters estimated. © 2006 Elsevier B.V. All rights reserved.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/93903
ISSN:	0022328X
DOI:	10.1016/j.jorganchem.2006.01.007
Appears in Collections:	Staff Publications

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