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Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2006.01.007
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dc.titleGroup 15 ligand migration in the heteronuclear clusters RuOs 3(μ-H)2(CO)12(EPh3) (E = P, As, Sb)
dc.contributor.authorPereira, L.J.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:29:48Z
dc.date.available2014-10-16T08:29:48Z
dc.date.issued2006-04-15
dc.identifier.citationPereira, L.J., Leong, W.K. (2006-04-15). Group 15 ligand migration in the heteronuclear clusters RuOs 3(μ-H)2(CO)12(EPh3) (E = P, As, Sb). Journal of Organometallic Chemistry 691 (9) : 1941-1944. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2006.01.007
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93903
dc.description.abstractThe monosubstituted clusters RuOs3(μ-H)2(CO) 12(EPh3) (where E = P, As, Sb) exhibit isomers in which the group 15 ligand is on an Os or an Ru vertex. Evidence is presented for hydride fluxionality and EPh3 ligand migration. These processes have been examined by variable temperature NMR studies, and the kinetic parameters estimated. © 2006 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2006.01.007
dc.sourceScopus
dc.subjectChemical exchange
dc.subjectGroup 15 ligand
dc.subjectHeterometallic complexes
dc.subjectLigand migration
dc.subjectOsmium
dc.subjectRuthenium
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2006.01.007
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume691
dc.description.issue9
dc.description.page1941-1944
dc.description.codenJORCA
dc.identifier.isiut000236929300018
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