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|Title:||On the use of cob(II) alamin as a spin trap in radical polymerization|
Di Lena, F.
|Source:||Ng, Y.-H., Di Lena, F., Chai, C.L.L. (2012-05). On the use of cob(II) alamin as a spin trap in radical polymerization. Macromolecular Research 20 (5) : 473-476. ScholarBank@NUS Repository. https://doi.org/10.1007/s13233-012-0039-9|
|Abstract:||Hydroxocobalamin reduced with ascorbic acid acts as a spin trap for free radical polymerization in water. The reaction mechanism is dependent on monomer type. An acrylic olefin such as 2-hydroxyethyl acrylate (HEA) is polymerized at pH 7 and in the presence of a conventional radical source mainly through reversible deactivation by a coupling mechanism. In contrast, a methacrylate like polyethylene glycol methacrylate undergoes catalytic chain transfer oligomerization.|
|Source Title:||Macromolecular Research|
|Appears in Collections:||Staff Publications|
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