Please use this identifier to cite or link to this item:
https://doi.org/10.1007/s13233-012-0039-9
DC Field | Value | |
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dc.title | On the use of cob(II) alamin as a spin trap in radical polymerization | |
dc.contributor.author | Ng, Y.-H. | |
dc.contributor.author | Di Lena, F. | |
dc.contributor.author | Chai, C.L.L. | |
dc.date.accessioned | 2014-10-29T01:56:13Z | |
dc.date.available | 2014-10-29T01:56:13Z | |
dc.date.issued | 2012-05 | |
dc.identifier.citation | Ng, Y.-H., Di Lena, F., Chai, C.L.L. (2012-05). On the use of cob(II) alamin as a spin trap in radical polymerization. Macromolecular Research 20 (5) : 473-476. ScholarBank@NUS Repository. https://doi.org/10.1007/s13233-012-0039-9 | |
dc.identifier.issn | 15985032 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/106179 | |
dc.description.abstract | Hydroxocobalamin reduced with ascorbic acid acts as a spin trap for free radical polymerization in water. The reaction mechanism is dependent on monomer type. An acrylic olefin such as 2-hydroxyethyl acrylate (HEA) is polymerized at pH 7 and in the presence of a conventional radical source mainly through reversible deactivation by a coupling mechanism. In contrast, a methacrylate like polyethylene glycol methacrylate undergoes catalytic chain transfer oligomerization. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1007/s13233-012-0039-9 | |
dc.source | Scopus | |
dc.subject | Bioorganometallics | |
dc.subject | Cobalamin | |
dc.subject | Radical polymerization | |
dc.subject | Sustainable chemistry | |
dc.type | Article | |
dc.contributor.department | PHARMACY | |
dc.description.doi | 10.1007/s13233-012-0039-9 | |
dc.description.sourcetitle | Macromolecular Research | |
dc.description.volume | 20 | |
dc.description.issue | 5 | |
dc.description.page | 473-476 | |
dc.identifier.isiut | 000303538700006 | |
Appears in Collections: | Staff Publications |
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