Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/98328
DC Field | Value | |
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dc.title | The v2 and v8 + v10 bands of CF2=CH2 | |
dc.contributor.author | Wang, W.F. | |
dc.contributor.author | Tan, T.L. | |
dc.contributor.author | Ong, P.P. | |
dc.date.accessioned | 2014-10-16T09:45:49Z | |
dc.date.available | 2014-10-16T09:45:49Z | |
dc.date.issued | 1997-01 | |
dc.identifier.citation | Wang, W.F.,Tan, T.L.,Ong, P.P. (1997-01). The v2 and v8 + v10 bands of CF2=CH2. Journal of Molecular Spectroscopy 181 (1) : 11-17. ScholarBank@NUS Repository. | |
dc.identifier.issn | 00222852 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/98328 | |
dc.description.abstract | The high-resolution FTIR spectrum of CF2=CH2 was measured and analyzed in the Fermi interacting v2 and v8 + v10 bands around 1735 cm-1. Both bands have strong infrared absorption with an A-type appearance. Watson's A-reduced Hamiltonian in the Ir representation was employed in the computation of the energy levels, taking into account the Fermi resonance contribution. A total of 2119 v2 transitions and 2056 v8 + v10 transitions were eventually assigned with a rms deviation of 0.00075 cm-1. In a nonlinear least-squares fit, accurate rovibrational constants of the upper states were determined with the band origins v2 = 1728.49829 ± 0.00005 cm-1 and v8 + v10 = 1741.50207 ± 0.00004 cm-1. Finally, a set of equilibrium rotational constants of CF2=CH2 were derived. © 1997 Academic Press, Inc. | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | PHYSICS | |
dc.description.sourcetitle | Journal of Molecular Spectroscopy | |
dc.description.volume | 181 | |
dc.description.issue | 1 | |
dc.description.page | 11-17 | |
dc.description.coden | JMOSA | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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