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|Title:||Pb 3O 4 type antimony oxides MSb 2O 4 (M = Co, Ni) as anode for Li-ion batteries||Authors:||Jibin, A.K.
Subba Rao, G.V.
|Issue Date:||1-Jun-2012||Citation:||Jibin, A.K., Reddy, M.V., Subba Rao, G.V., Varadaraju, U.V., Chowdari, B.V.R. (2012-06-01). Pb 3O 4 type antimony oxides MSb 2O 4 (M = Co, Ni) as anode for Li-ion batteries. Electrochimica Acta 71 : 227-232. ScholarBank@NUS Repository. https://doi.org/10.1016/j.electacta.2012.03.145||Abstract:||Polycrystalline samples of isostructural MSb 2O 4 (M = Co, Ni) have been prepared by solid state synthesis and lithium-storage is investigated as possible anode materials for lithium-ion batteries. The reaction mechanism of lithium with MSb 2O 4 (M = Co, Ni) is explored by galvanostatic cycling, cyclic voltammo-gram and ex situ studies. Both CoSb 2O 4 and NiSb 2O 4 exhibit similar electrochemical behavior and show reversible capacity of 490 and 412 mAhg -1 respectively in the first cycle. Reversible alloying de-alloying of Li x Sb takes place in an amorphous matrix of M (Co, Ni) and Li 2O during electrochemical cycling. © 2012 Elsevier Ltd. All rights reserved.||Source Title:||Electrochimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/97503||ISSN:||00134686||DOI:||10.1016/j.electacta.2012.03.145|
|Appears in Collections:||Staff Publications|
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