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Alternative Title
Abstract
Crystallizing growth: The initial structure of crystal unclei is supersaturation-dependent. At low degrees of supersaturation, liquid-like nuclei are formed initially, which undergo a continuous structure transition from liquid-like to crystal-like as the size N increases. This gradual structure evolution substantially lowers the nucleation barrier ΔGz.ast; and facilitates the nucleation relative to the formation of crystal-like clusters from the beggining. © 2009 Wiley-VCH Verleg GmbH & Co. KGaA.
Keywords
Colloids, Crystal engineering, Crystal growth, Nucleation
Source Title
Angewandte Chemie - International Edition
Publisher
Series/Report No.
Collections
Rights
Date
2009-02-02
DOI
10.1002/anie.200804743
Type
Article