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|Title:||Molecular orientation and ordering during initial growth of copper phthalocyanine on Si(111)||Authors:||Wang, L.
|Issue Date:||1-Mar-2007||Citation:||Wang, L., Qi, D., Liu, L., Chen, S., Gao, X., Wee, A.T.S. (2007-03-01). Molecular orientation and ordering during initial growth of copper phthalocyanine on Si(111). Journal of Physical Chemistry C 111 (8) : 3454-3458. ScholarBank@NUS Repository. https://doi.org/10.1021/jp066600n||Abstract:||The molecular orientation and order in the initial growth of copper phthalocyanine on Si(111) was investigated in situ by angular-dependent X-ray absorption spectroscopy. A transition from lying-down to standing-up configuration occurs in less than one monolayer. After the Si surface is passivated by a monolayer of the molecules, only the standing-up structure persists in subsequent growth. The molecular film also exhibits an order - disorder - order transition in the distribution of molecular tilt angle during growth. These transitions are related to the changes of interactions in the system at different stages. © 2007 American Chemical Society.||Source Title:||Journal of Physical Chemistry C||URI:||http://scholarbank.nus.edu.sg/handle/10635/97251||ISSN:||19327447||DOI:||10.1021/jp066600n|
|Appears in Collections:||Staff Publications|
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