Mixed oxides Ca2Fe2O5 and Ca 2Co2O5 as anode materials for Li-ion batteries

Abstract

The electrochemical performance of mixed oxides, Ca2Fe 2O5 and Ca2Co2O5 for use in Li-ion batteries was studied with Li as the counter electrode. The compounds were prepared and characterized by X-ray diffraction and SEM. Ca 2Fe2O5 showed a reversible capacity of 226 mAh/g at the 14th cycle and retained 183 mAh/g at the end of 50 cycles at 60 mA/g in the voltage window 0.005-2.5 V. A reversible capacity in the range, 365-380 mAh/g, which is stable up to 50 charge-discharge cycles is exhibited by Ca2Co2O5 in the voltage window, 0.005-3.0 V and at 60 mA/g. This corresponds to recycleable moles of Li of 3.9 ± 0.1 (theoretical: 4.0). Significant improvement in the cycling performance and attainable reversible capacity were noted for Ca2Co2O 5 on cycling to an upper cut-off voltage of 3.0 V as compared to 2.5 V. Coulombic efficiency for both compounds is >98%. Electrochemical impedance spectroscopy (EIS) data clearly indicate the reversible formation/decomposition of polymeric surface film on the electrode surface of Ca2Co2O5 in the voltage window, 0.005-3.0 V. Cyclic voltammetry results compliment the galvanostatic cycling data. © 2003 Published by elsevier Ltd.