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Title: High resolution FTIR spectrum of the v1 band of bromochloromethane
Authors: Wang, W.F.
Tan, T.L. 
Tan, B.L.
Ong, P.P. 
Keywords: Least-square fitting
Q branch
Issue Date: Mar-1996
Citation: Wang, W.F.,Tan, T.L.,Tan, B.L.,Ong, P.P. (1996-03). High resolution FTIR spectrum of the v1 band of bromochloromethane. Spectrochimica Acta - Part A Molecular Spectroscopy 52 (3) : 337-342. ScholarBank@NUS Repository.
Abstract: The IR spectrum of the v1 band of natural bromochloromethane (CH2BrCl) has been recorded at a resolution of 0.008 cm-1 in the region 2940-3060 cm-1 on a BOMEM DA3.002 Fourier-transform spectrometer. The rovibrational analysis on the strong Q branch of this B-type band has been performed in the prolate symmetry top approximation due to the fairly small difference between constants B and C. A normal linear least-square fitting of the identified P,RQK(J) clusters provided the corresponding excited state molecular parameters for three of the four naturally existing isotopomers of bromochloromethane with a standard error of about 0.02cm-1.
Source Title: Spectrochimica Acta - Part A Molecular Spectroscopy
ISSN: 05848539
Appears in Collections:Staff Publications

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