Please use this identifier to cite or link to this item:
|Title:||Synthesis and structural characterization of palladium dicarbene complexes bearing labile co-ligands||Authors:||Huynh, H.V.
|Issue Date:||2009||Citation:||Huynh, H.V., Seow, H.X. (2009). Synthesis and structural characterization of palladium dicarbene complexes bearing labile co-ligands. Australian Journal of Chemistry 62 (9) : 983-987. ScholarBank@NUS Repository. https://doi.org/10.1071/CH09143||Abstract:||Dicarbene complexes [Pd(OAc)2(diNHC)] (2), [Pd(O 2CCF3)2(diNHC)] (3), and [Pd(CNCH 3)2(diNHC)](SO3CF3)2 (4) bearing labile acetato, fluoroacetato, and acetonitrile co-ligands have been synthesized via metathesis reaction of the respective precursor [PdBr 2(diNHC)] (1) with Ag-salts. All complexes are stable towards air and moisture and have been fully characterized by spectroscopic and spectrometric methods. Notably and in comparison to diphosphine analogues, they resist ligand disproportionation in solution. Their molecular structures have also been determined by single crystal X-ray diffraction. A preliminary catalytic study showed low activity in the hydroamination reaction, but revealed an interesting co-ligand influence. © CSIRO 2009.||Source Title:||Australian Journal of Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/95508||ISSN:||00049425||DOI:||10.1071/CH09143|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Oct 16, 2020
WEB OF SCIENCETM
checked on Oct 8, 2020
checked on Oct 11, 2020
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.