Please use this identifier to cite or link to this item:
https://doi.org/10.1071/CH13224
Title: | Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling | Authors: | Bai, S.-Q. Jiang, L. Zuo, J.-L. Yan, C.-H. Hor, T.S.A. |
Issue Date: | 2013 | Citation: | Bai, S.-Q., Jiang, L., Zuo, J.-L., Yan, C.-H., Hor, T.S.A. (2013). Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling. Australian Journal of Chemistry 66 (9) : 1029-1033. ScholarBank@NUS Repository. https://doi.org/10.1071/CH13224 | Abstract: | A new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO. | Source Title: | Australian Journal of Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95450 | ISSN: | 00049425 | DOI: | 10.1071/CH13224 |
Appears in Collections: | Staff Publications |
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