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Title: Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling
Authors: Bai, S.-Q.
Jiang, L.
Zuo, J.-L.
Yan, C.-H.
Hor, T.S.A. 
Issue Date: 2013
Citation: Bai, S.-Q., Jiang, L., Zuo, J.-L., Yan, C.-H., Hor, T.S.A. (2013). Dinuclear Cu(ii) 1,2,3-Triazole-Bridged Complex with Ferromagnetic Coupling. Australian Journal of Chemistry 66 (9) : 1029-1033. ScholarBank@NUS Repository.
Abstract: A new dinuclear Cu(ii) complex [Cu2Cl4(L1) 2] (1) (L1≤1-(2-picolyl)-4-hexyl-1H-1,2,3-triazole) has been synthesised and characterised by single-crystal X-ray diffraction (XRD) and powder XRD, thermogravimetric analysis, electron paramagnetic resonance spectrum, photoluminescence, and magnetic measurements. Complex 1 shows double 1,2,3-triazoles bridging the dinuclear Cu2N4 moiety, in which the bridging N≤N bond indicates basal-apical asymmetric mode with 112.6° torsion angle of Cu-N≤N-Cu. Different from most azole-bridged dinuclear Cu(ii) with antiferromagnetic couplings, complex 1 shows an intramolecular weak ferromagnetic interaction (J≤0.91cm-1). © 2013 CSIRO.
Source Title: Australian Journal of Chemistry
ISSN: 00049425
DOI: 10.1071/CH13224
Appears in Collections:Staff Publications

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