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Title: Triethylammonium tris(thiobenzoato-O,S)-cadmate(II)
Authors: Vittal, J.J. 
Dean, P.A.W.
Issue Date: 15-Mar-1998
Citation: Vittal, J.J.,Dean, P.A.W. (1998-03-15). Triethylammonium tris(thiobenzoato-O,S)-cadmate(II). Acta Crystallographica Section C: Crystal Structure Communications 54 (3) : 319-321. ScholarBank@NUS Repository.
Abstract: The synthesis and structure of the title compound, (C6H16N)[Cd(C7H5OS)3], are reported. There are two independent formula units in the asymmetric unit. In each [Cd{S(O)CPh}3]- anion, the CdII atom is located in the plane of the three S atoms. The Cd-S distances are 2.489 (1), 2.496 (1) and 2.547 (1) Å in ion-pair (1), and 2.505 (1), 2.515 (1) and 2.592 (1) Å in ionpair (2). In addition, there are weak intramolecular interactions between the Cd and carbonyl O atoms [Cd⋯O 2.537 (2), 2.663 (2) and 3.111 (2) Å in (1), and 2.464 (2), 2.677 (2) and 2.718 (2) Å in (2)]. Each cationanion pair is linked by a strong N-H⋯O hydrogen bond, with respective O⋯H and O⋯N distances of 1.925 (3) and 2.834 (3) Å in (1), and 1.886 (2) and 2.789 (2) Å in (2).
Source Title: Acta Crystallographica Section C: Crystal Structure Communications
ISSN: 01082701
Appears in Collections:Staff Publications

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