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|Title:||Trans [OR=eV-OH] core stabilised by chelating N-heterocyclic dicarbene ligands||Authors:||Lum, R.
|Issue Date:||28-Jan-2013||Citation:||Lum, R., Zhang, H., Zhang, W., Bai, S.-Q., Zhao, J., Hor, T.S.A. (2013-01-28). Trans [OR=eV-OH] core stabilised by chelating N-heterocyclic dicarbene ligands. Dalton Transactions 42 (4) : 871-873. ScholarBank@NUS Repository. https://doi.org/10.1039/c2dt31681a||Abstract:||Three Re(v) N-heterocyclic carbene complexes [ReO(OH)(LMe) 2][PF6]1.4[ReO4]0.6, [ReO(OH)(LiPr)2][PF6]1.4[ReO 4]0.6 and [ReO(OH)(LBn)2][PF 6]1.3[ReO4]0.7 (LMe = 1,1′-methylene-bis(3-methylimidazole-2-ylidene); LiPr = 1,1′-methylene-bis(3-isopropylimidazole-2-ylidene) and LBn = 1,1′-methylene-bis(3-benzylimidazole-2-ylidene)) with trans oxo and hydroxo at axial positions have been synthesized. © The Royal Society of Chemistry 2013.||Source Title:||Dalton Transactions||URI:||http://scholarbank.nus.edu.sg/handle/10635/95336||ISSN:||14779226||DOI:||10.1039/c2dt31681a|
|Appears in Collections:||Staff Publications|
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