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Title: Trans [OR=eV-OH] core stabilised by chelating N-heterocyclic dicarbene ligands
Authors: Lum, R.
Zhang, H.
Zhang, W.
Bai, S.-Q.
Zhao, J. 
Hor, T.S.A. 
Issue Date: 28-Jan-2013
Citation: Lum, R., Zhang, H., Zhang, W., Bai, S.-Q., Zhao, J., Hor, T.S.A. (2013-01-28). Trans [OR=eV-OH] core stabilised by chelating N-heterocyclic dicarbene ligands. Dalton Transactions 42 (4) : 871-873. ScholarBank@NUS Repository.
Abstract: Three Re(v) N-heterocyclic carbene complexes [ReO(OH)(LMe) 2][PF6]1.4[ReO4]0.6, [ReO(OH)(LiPr)2][PF6]1.4[ReO 4]0.6 and [ReO(OH)(LBn)2][PF 6]1.3[ReO4]0.7 (LMe = 1,1′-methylene-bis(3-methylimidazole-2-ylidene); LiPr = 1,1′-methylene-bis(3-isopropylimidazole-2-ylidene) and LBn = 1,1′-methylene-bis(3-benzylimidazole-2-ylidene)) with trans oxo and hydroxo at axial positions have been synthesized. © The Royal Society of Chemistry 2013.
Source Title: Dalton Transactions
ISSN: 14779226
DOI: 10.1039/c2dt31681a
Appears in Collections:Staff Publications

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