Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.jorganchem.2007.07.023
| DC Field | Value | |
|---|---|---|
| dc.title | The synthesis and reactivity of some indenyl and bis-indenyl ruthenium carbonyl complexes | |
| dc.contributor.author | Sridevi, V.S. | |
| dc.contributor.author | Leong, W.K. | |
| dc.date.accessioned | 2014-10-16T08:45:49Z | |
| dc.date.available | 2014-10-16T08:45:49Z | |
| dc.date.issued | 2007-10-15 | |
| dc.identifier.citation | Sridevi, V.S., Leong, W.K. (2007-10-15). The synthesis and reactivity of some indenyl and bis-indenyl ruthenium carbonyl complexes. Journal of Organometallic Chemistry 692 (22) : 4909-4916. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2007.07.023 | |
| dc.identifier.issn | 0022328X | |
| dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/95267 | |
| dc.description.abstract | The reaction of [Ru3(CO)12] (1), with indene in refluxing xylene affords [{(η5-C9H7)Ru(CO)2}2] (2), in high yield. An analogous reaction of 1 with 2-phenylindene affords the expected dinuclear complex [{(η5-C9H6Ph)Ru(CO)2}2] (5), and a heptaruthenium cluster [(C9H4Ph)Ru7(μ-H)(μ-CO)2(CO)16] (6). The indenyl ligand in compound 6 exhibits a novel bonding mode in which the benzenoid ring is μ4,η1:η1:η2:η2 bound to the cluster. Refluxing 1 with bis-indenyl methane affords the dinuclear complex [Ru2(CO)4{μ-(η5-C9H6)2CH2}] (7), which reacts with iodine via Ru-Ru bond cleavage to give [Ru2I2(CO)4{(η5-C9H6)2CH2}] (8). © 2007 Elsevier B.V. All rights reserved. | |
| dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2007.07.023 | |
| dc.source | Scopus | |
| dc.subject | Bis-indenyl | |
| dc.subject | Cluster | |
| dc.subject | Indenyl | |
| dc.subject | Ruthenium | |
| dc.type | Article | |
| dc.contributor.department | CHEMISTRY | |
| dc.description.doi | 10.1016/j.jorganchem.2007.07.023 | |
| dc.description.sourcetitle | Journal of Organometallic Chemistry | |
| dc.description.volume | 692 | |
| dc.description.issue | 22 | |
| dc.description.page | 4909-4916 | |
| dc.description.coden | JORCA | |
| dc.identifier.isiut | 000250741200013 | |
| Appears in Collections: | Staff Publications | |
Show simple item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.